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Porous Nanographenes, Graphene Nanoribbons, and Nanoporous Graphene Selectively Synthesized from the Same Molecular Precursor J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-15 Mamun Sarker, Christoph Dobner, Percy Zahl, Christian Fiankor, Jian Zhang, Anshul Saxena, Narayana Aluru, Axel Enders, Alexander Sinitskii
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Charge Transfer Mechanism on a Cobalt-Polyoxometalate-TiO2 Photoanode for Water Oxidation in Acid J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-15 Fengyi Zhao, Ting Cheng, Xinlin Lu, Nandan Ghorai, Yiwei Yang, Yurii V. Geletii, Djamaladdin G. Musaev, Craig L. Hill, Tianquan Lian
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Droplet Polymer Bilayers for Bioelectronic Membrane Interfacing J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-15 Emily A. Schafer, Joshua J. Maraj, Camryn Kenney, Stephen A. Sarles, Jonathan Rivnay
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Breaking of Lateral Symmetry in Two-Dimensional Crystallization-Driven Self-Assembly on a Surface J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-15 Geyu Lin, Jiawei Tao, Yan Sun, Yan Cui, Ian Manners, Huibin Qiu
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Carbon Nanotubes as a Solid-State Electron Mediator for Visible-Light-Driven Z-Scheme Overall Water Splitting J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-15 Lihua Lin, Yiwen Ma, Nobuyuki Zettsu, Junie Jhon M. Vequizo, Chen Gu, Akira Yamakata, Takashi Hisatomi, Tsuyoshi Takata, Kazunari Domen
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Enzymatic Reaction-Coupled, Cooperative Supramolecular Polymerization J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-15 Angshuman Das, Saikat Ghosh, Ananya Mishra, Arka Som, Vijay Basavaraj Banakar, Sarit S. Agasti, Subi J. George
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Self-Limiting Phase Transition Enabling Reversible Overstoichiometric Li Storage in Ni-Rich Cathodes J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-15 Xin-Hai Meng, Dongdong Xiao, Zi-Yi Zhou, Wen-Zhe Liu, Ji-Lei Shi, Li-Jun Wan, Yu-Guo Guo
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Self-Trapped Exciton Emission in Highly Polar 0D Hybrid Ammonium/Hydronium-Based Perovskites Triggered by Antimony Doping J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-14 Bo Zhou, Feier Fang, Zexiang Liu, Haizhe Zhong, Kang Zhou, Hanlin Hu, Jiacheng Min, Fangyuan Zheng, Shaofan Fang, Jingheng Nie, Jing-Kai Huang, Lain-Jong Li, Henan Li, Yi Wan, Yumeng Shi
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Direct Observation of Gas-Phase Hydroxymethylene: Photoionization and Kinetics Resulting from Methanol Photodissociation J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-14 Emily K. Hockey, Nathan McLane, Carles Martí, LeAnh Duckett, David L. Osborn, Leah G. Dodson
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Effect of Dynamic and Preferential Decoration of Pt Catalyst Surfaces by WOx on Hydrodeoxygenation Reactions J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-13 Justin Marlowe, Siddharth Deshpande, Dionisios G. Vlachos, Mahdi M. Abu-Omar, Phillip Christopher
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An Extended Superstructure-Based Model for Synthesis of Compression-Heat-Integrated Heat Exchanger Networks Coupled with Multiple Utilities Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-15 Yongjian Huang, Yafeng Xing, Yu Zhuang, Jian Du
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A Novel Fault Diagnosis Framework for Industrial Production Processes Based on Causal Network Inference Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-15 Jiaxin Zhang, Gade Pandu Rangaiah, Lichun Dong, Lakshminarayanan Samavedham
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Demineralization of Oxalic Acid Solutions by Anodic Oxidation in a Stirred Tank Electrochemical Reactor: Experimental and Modeling Study Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-15 Iman El Gheriany, Mohamed Helmy Abdel-Aziz, El-Sayed Zakaria El-Ashtoukhy, Gomaa H. Sedahmed
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Reaction Network and Byproduct Formation in Ethylene Oxychlorination on K-Doped CuCl2/γ-Al2O3 Catalyst Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-15 Wei Zhang, Yalan Wang, Kumar Ranjan Rout, Tigran Margossian, De Chen
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Carbonaceous Skin-Optimized Reversibility of Bismuth- and Antimony-Based Selenide as an Ultrastable Anode for Potassium Ion Storage Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Yuliang Yang, Suqin Liu, Quanrong Pan, Weiwei Zhu, Jue Wang
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Synthesis of CaC2 and the Adsorption Mechanism of Alkaline Metals on the CaC2 Surface Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Jia Lv, Tao Yang, Maierhaba Abudoureheman, Bo Wei, Lanzhen He, Quan Zhu, Jinrong Ma, Yanfeng Cheng
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Photoswitchable Catalytic Aerobic Oxidation of Biomass-Based Furfural: A Selective Route for the Synthesis of 5-Hydroxy-2(5H)-furanone and Maleic Acid by Using the CdS/MOF Photocatalyst Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Saeede Saki, Mona Hosseini-Sarvari, Yanlong Gu, Tianjian Zhang
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Upgrading of Aqueous Ethanol to Long-Chain Alcohols over Immobilized Highly Dispersed Ni–Re Catalyst Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Qian Zhang, Wenjun Liu, Shan Jiang, Minjun Kuang, Jiajin Li, Songbai Qiu, Xiaoping Wu
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Process Optimization and Kinetic Modeling for Sucrose Acylation to Sucrose-6-acetate through the Dibutyltin Oxide Method Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Minghua Yang, Zhihong Ma, Lejian Chen, Weizhen Sun, Ling Zhao
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Highly and Uniformly Thermal Conductive Phase Change Composites by Constructing the Bidirectionally Oriented and Interconnected Boron Nitride Nanosheet Network Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Zhi-Guo Wang, Jun-Yang Wang, Zi-Han Guo, Wei-Hang Wang, Si-Yuan Zhou, Yue Li, Li-Chuan Jia, Jia-Hong Niu, Gan-Ji Zhong, Ling Xu, Jia-Zhuang Xu, Zhong-Ming Li
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Biphasic Plasma Microreactor for Oxyfunctionalization of Liquid Hydrocarbons Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Darien K. Nguyen, Fabio Cameli, Panagiotis Dimitrakellis, Dionisios G. Vlachos
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Coke Formation in Steam Cracking Reactors: Deciphering the Impact of Aromatic Compounds and Temperature on Fouling Dynamics Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Hamed Mohamadzadeh Shirazi, Lucas dos Santos Vargette, Georgios Bellos, Yannick Ureel, Melissa N. Dunkle, Steven Corthals, Marie-Françoise Reyniers, Kevin M. Van Geem
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NOx Reduction in a Cement Kiln with Spent Pot Lining: A Reaction Kinetics Study on HCN–NO and HNC–NO Interactions Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Manjusha C. Padole, Abhijeet Raj
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Site-Specific Activity Maps Observed during Methanol-to-Olefin Conversion over ZSM-5 Catalysts Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-14 Toyin Omojola
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Optimizing Fucoidan Encapsulation in a W1/O/W2 Double Emulsion through an Ultrasound-Assisted Process and Response Surface Methodology Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-13 Uday D. Bagale, Ammar Kadi, Artem Malinin, Irina Potoroko, Varisha Anjum, Shirish. H. Sonawane
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Multiobjective Optimization of Spiral Guide Vanes for Boosting Separation Performance of Cyclone Separators Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-13 Gang Cao, Guogang Sun, Shiwei Yuan, Yunpeng Yue, Yingyi Wu
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Characteristics of the Particle Break Process and Its Mechanism Analysis in Fluidized Process Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-13 Dan Zhu, Xingyang Zeng, Chen Song, Caifu Li, Jun Chen, Jingjun Guan, Fang Liu, Li Yang
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PVDF-HFP-Based Pioneering Anion Exchange Membranes for Advanced Sulfuric Acid Enrichment with Reduced Water Mobility Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-13 Shuaijun Yu, Yazhen Jiang, Geting Xu, Hongyu Liu, Edison Huixiang Ang, Junbin Liao, Jiangnan Shen
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Molybdenum-Promoted CuMn2O4 Oxygen Carrier for Chemical Looping Oxidative Dehydrogenation of Ethane Ind. Eng. Chem. Res. (IF 4.2) Pub Date : 2024-05-10 Guochao Hu, Zhiyang Yu, Yongzhuo Liu, Yanxia Wang, Qingjie Guo
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Corrigendum: Electrochemical Nickel‐Catalyzed Hydrogenation Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15
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Corrigendum: Electrochemical Nickel‐Catalyzed Hydrogenation Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15
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Chemoenzymatic Synthesis of 2‐Aryl Thiazolines from 4‐Hydroxybenzaldehydes Using Vanillyl Alcohol Oxidases Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Haowen Zhang, Shuhan Xie, Jun Yang, Ning Ye, Feng Gao, Fabrice Gallou, Lei Gao, Xiaoguang Lei
Nitrogen heterocycles are commonly found in bioactive natural products and drugs. However, the biocatalytic tools for nitrogen heterocycle synthesis are limited. Herein, we report the discovery of vanillyl alcohol oxidases (VAOs) as efficient biocatalysts for the one‐pot synthesis of 2‐aryl thiazolines from various 4‐hydroxybenzaldehydes and aminothiols. The wild‐type biocatalyst features a broad scope
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Strong Swelling and Symmetrization in Siliceous Zeolites due to Hydrogen Insertion at High Pressure Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Mario Santoro, Jérôme Rouquette, Marco Fabbiani, Francesco di Renzo, Benoît Coasne, Weiwei Dong, Konstantin Glazyrin, Julien Haines
Hydrogen and helium saturate the 1D pore systems of the high‐silica (Si/Al>30) zeolites Theta‐One (TON), and Mobile‐Twelve (MTW) at high pressure based on x‐ray diffraction, Raman spectroscopy and Monte Carlo simulations. In TON, a strong 22% volume increase occurs above 5 GPa with a transition from the collapsed P21 to a symmetrical, swelled Cmc21 form linked to an increase in H2 content from 12 H2/unit
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Enantioselective Synthesis of Sulfinamidines via Asymmetric Nitrogen Transfer from N‐H Oxaziridines to Sulfenamides Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Marc Fimm, Fumito Saito
Sulfinamidines are promising aza‐SIV chiral building blocks in asymmetric synthesis and drug discovery. However, no report has documented their enantioselective synthesis. Here we present an enantioselective synthesis of sulfinamidines via electrophilic amination of sulfenamides using an enantiopure N‐H oxaziridine. The resulting enantiomerically enriched primary sulfinamidines are configurationally
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On Tautomerism and Amphoterism: An In‐Depth Structural and Physicochemical Characterization of Ammeline and Some of Its Salts Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Thaddäus Koller, Simon M.J. Endraß, Markus Rösch, Kristian Witthaut, Thomas M. Klapötke, Wolfgang Schnick
Ammeline is a simple, readily available, molecular compound, which has been known for nearly 200 years. Despite that, no proper structural characterization of ammeline has been conducted so far. For this reason, the prevalent tautomeric form of ammeline in the solid remained unknown to this date. In the course of this study, its crystal structure was finally established by single‐crystal X‐ray diffraction
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An Enzymatic Prodrug‐like Route to Thio and Selenoamides Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Keishi Ishida, Agnieszka Litomska, Kyle L. Dunbar, Christian Hertweck
6‐Thioguanine (6TG) is a clinically used antitumor agent that was rationally designed as a DNA‐targeting antimetabolite, but it also occurs naturally. 6TG is a critical virulence factor produced by Erwinia amylovorans, a notorious plant pathogen that causes fire blight of pome fruit trees. The biosynthesis of the rare thioamide metabolite involves an adenylating enzyme (YcfA) and a sulfur‐mobilizing
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All‐Inorganic sp‐Chain Ligands: Isoelectronic B/N Analogues of E. O. Fischer's Alkynylcarbynes Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Luis Walter, Krzysztof Radacki, Rian Dewhurst, Rüdiger Bertermann, Maik Finze, Holger Braunschweig
Borylation of a tungsten‐bound N2 ligand and halide abstraction provides access to a cationic complex with an unprecedented linear NNBR ligand. This complex undergoes [3+2] cycloaddition with azides, and an unexpected chain‐extension reaction with an iminoborane, leading to a complex with a five‐atom B/N chain. These two [NNBR]‐containing complexes, inorganic analogues of E. O. Fischer's alkynylcarbynes
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Hidden Impurities Generate False Positives in Single Atom Catalyst Imaging Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Nicolò Allasia, Sean Michael Collins, Quentin Mathieu Ramasse, Gianvito Vilé
Single‐atom catalysts (SACs) are an emerging class of materials, leveraging maximum atom utilization and distinctive structural and electronic properties to bridge heterogeneous and homogeneous catalysis. Direct imaging methods, such as aberration‐corrected high‐angle annular dark‐field scanning transmission electron microscopy, are commonly applied to confirm the atomic dispersion of active sites
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Enantioselective Synthesis of Heteroatom‐Linked Non‐Biaryl Atropisomers Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Abdelati Naghim, Jean RODRIGUEZ, Olivier Chuzel, Gaëlle Chouraqui, Damien Bonne
Atropisomers hold significant fascination, not only for their prevalence in natural compounds but also for their biological importance and wide‐ranging applications as chiral materials, ligands, and organocatalysts. While biaryl and heterobiaryl atropisomers are commonly studied, the enantioselective synthesis of less abundant heteroatom‐linked non‐biaryl atropisomers presents a formidable challenge
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Lone‐Pair‐p Bond Strength Unveiled by a Combined Experimental and Computational Study Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Cristian L. Gutiérez-Peña, Ana Gutiérrez-Blanco, Dmitry G. Gusev, Macarena Poyatos, Eduardo Victor Peris
A series of naphthalene‐diimide (NDI) and perylene‐diimide (PDI) connected bis‐N‐heterocyclic carbene complexes of iridium (III) have been prepared and fully characterized. The analysis of their NMR spectroscopic features, together their molecular structures show that these species display lone pair‐p interactions between the chloride ligands of the Ir(III) complex and the heterocycles of the NDI/PDI
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Constructing High‐performance Cobalt‐based Environmental Catalysts from Spent Lithium‐Ion Batteries: Unveiling Overlooked Roles of Copper and Aluminum from Current Collectors Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Jianxing Liang, Kan Li, Feng Shi, Jingdong Li, Jia-nan Gu, Yixin Xue, Chenyu Bao, Mingming Guo, Jinping Jia, Maohong Fan, Tonghua Sun
Converting spent lithium‐ion batteries (LIBs) cathode materials into environmental catalysts has drawn more and more attention. Herein, we fabricated a Co3O4‐based catalyst from spent LiCoO2 LIBs (Co3O4‐LIBs) and found that the role of Al and Cu from current collectors on its performance is nonnegligible. The density functional theory calculations confirmed that the doping of Al and/or Cu upshifts
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[22]Pentaphyrins(2.0.1.1.0) Displaying N‐Fusion, Pyrrole‐Rearrangement, and Dimerization Reactions Upon Oxidation and Metalation Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Jinchao Chen, Le Liu, Yutao Rao, Ling Xu, Mingbo Zhou, Bangshao Yin, Soji Shimizu, Daiki Shimizu, Atsuhiro Osuka, Jianxin Song
Exploration of expanded porphyrins with unprecedented reactivities has remained important. Here [22]pentaphyrins(2.0.1.1.0) were synthesized as a constitutional isomer of sapphyrin by acid‐catalyzed cyclization of 1,14‐dibromo‐5,10‐diaryltripyrrin with 1,2‐di(pyrro‐2‐ly)ethenes. These pentaphyrins display roughly planar structures and varying aromaticities depending upon the vinylene structures. The
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Highly Stable MOF‐Type Lead Halide Luminescent Ferroelectrics Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Chen Sun, Yukong Li, Jinlin Yin, Dongyang Li, Chao Wu, Chi Zhang, Honghan Fei
Lead halide molecular ferroelectrics represent an important class of luminescent ferroelectrics, distinguished by their high chemical and structural tunability, excellent processability and distinctive luminescent characteristics. However, their inherent instability, prone to decomposition upon exposure to moisture and light, hinders their broader ferroelectric applications. Herein, for the first time
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A Processible and Ultrahigh‐temperature Organic Photothermal Material through Spontaneous and Quantitative [2+2] Cycloaddition–Cycloreversion Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Pengbo Han, He Xu, Guiquan Zhang, Anjun Qin, Ben Zhong Tang
Energy conversion, particularly light to heat conversion, has garnered significant attention owing to its prospect in renewable energy exploitation and utilization. Most previous efforts have focused on developing organic photothermal materials for low‐temperature applications, whereas the importance of simplifying the preparation methods of photothermal materials and enhancing their maximum photothermal
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π‐Conjugated Nanohoops: A new generation of curved materials for organic electronics Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Rupam ROy, clement Brouillac, emmanuel jacques, cassandre Quinton, Cyril Poriel
Nanohoops, cyclic association of π‐conjugated systems to form a hoop‐shaped molecule, have been widely developed in the last 15 years. Beyond the synthetic challenge, the strong interest towards these molecules arise from their radially‐oriented π‐orbitals, which provide singular properties to these fascinating structures. Thanks to their particular cylindrical arrangement, this new generation of curved
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Strong and Tough MXene Bridging‐induced Conductive Nacre Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Jia Yan, Tianzhu Zhou, Xinyu Yang, Zejun Zhang, Lei Li, Zhaoyong Zou, Zhengyi Fu, Qunfeng Cheng
Nacre is a classic model, providing an inspiration for fabricating high‐performance bulk nanocomposites with the two‐dimensional platelets. However, the “brick” of nacre, aragonite platelet, is an ideal building block for making high‐performance bulk nanocomposites. Herein, we demonstrated a strong and tough conductive nacre through reassembling aragonite platelets with bridged by MXene nanosheets
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Controlling Tin Halide Perovskite Oxidation Dynamics in Solution for Perovskite Optoelectronic Devices Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Mohammad Kahaj Khaja Nazeeruddin, Shun Tian, Guixiang Li, Roland C. Turnell-Ritson, Zhaofu Fei, Aurélien Bornet, Paul J. Dyson
As a leading contender to replace lead halide perovskites, tin‐based perovskites have demonstrated ever increasing performance in solar cells and light‐emitting diodes (LEDs). They tend to be processed with dimethyl sulfoxide (DMSO) solvent, which has been identified as a major contributor to the Sn(II) oxidation during film fabrication, posing a challenge to the further improvement of Sn‐based perovskites
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Alumina ‐ Stabilized SEI and CEI in Potassium Metal Batteries Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Pengcheng Liu, Hongchang Hao, Aditya Singla, Bairav S. Vishnugopi, John Watt, Partha P. Mukherjee, David Mitlin
Aluminum oxide (Al2O3) nanopowder is spin‐coated onto both sides of commercial polypropene separator to create artificial solid‐electrolyte interphase (SEI) and artificial cathode electrolyte interface (CEI) in potassium metal batteries (KMBs). This significantly enhances the stability, including of KMBs with Prussian Blue (PB) cathodes. For example, symmetric cells are stable after 1,000 cycles at
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Ionic Hydrogen Bond‐Assisted Catalytic Construction of Nitrogen Stereogenic Center via Formal Desymmetrization of Remote Diols Angew. Chem. Int. Ed. (IF 16.6) Pub Date : 2024-05-15 Zhongfu Luo, Minghong Liao, Wei Li, Sha Zhao, Kun Tang, Pengcheng Zheng, Yonggui Robin Chi, Xinglong Zhang, Xingxing Wu
The control of noncarbon stereogenic centers is of profound importance owing to their enormous interest in bioactive compounds and chiral catalyst or ligand design for enantioselective synthesis. Despite various elegant approaches have been achieved for construction of S‐, P‐, Si‐ and B‐stereocenters over the past decades, the catalyst‐controlled strategies to govern the formation of N‐stereogenic
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Sweat-adaptive adhesive hydrogel electronics enabled by dynamic hydrogen bond networks Chem. Eng. J. (IF 15.1) Pub Date : 2024-05-15 Siheng Wang, Zhuomin Wang, Lei Zhang, Zhanqian Song, He Liu, Xu Xu
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Laser-induced electro-response of oil shale: Principles and applications Chem. Eng. J. (IF 15.1) Pub Date : 2024-05-15 Xuecong Liu, Yuqi Jiao, Zhengchun Hong, Xue Peng, Zhiqing Lu, Kun Zhao, Xinyang Miao
This study introduces a laser-induced electro-response (LIER) method to address the challenges arising from the harsh detection environment and energy consumption in the conversion engineering of oil shale. LIER system with pulsed laser and continuous-wave laser was used to investigate the feasibility of oil yield detection and real-time pyrolysis characterization, respectively. The equivalent circuit
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H2O2 self-supplied CuFeOx nanosystem as fenton-like reaction agents for endogenous/exogenous responsive synergetic antibacterial therapy Chem. Eng. J. (IF 15.1) Pub Date : 2024-05-15 Lei Zhao, Yawen Chen, Qinglin Wei, Xinyi Lv, Ying Cui, Wenjun Wang, Xiaozhou Mou, Xuejiao Song, Xiaochen Dong, Yu Cai
Chemodynamic therapy (CDT) based on nanozyme has attracted extensive attention in the treatment of bacterial infections. However, the catalytic activity of nanozymes and the infection microenvironments severely limit CDT antibacterial efficacy. Herein, a near-infrared-controlled antibacterial nanoplatform (CuFeO/IR825@PCM) is developed by encapsulating Cu-Fe peroxide nanoparticles (CuFeO) and the photothermal
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Application of volume‐translated rescaled perturbed‐chain statistical associating fluid theory equation of state to pure compounds using an expansive experimental database AlChE J. (IF 3.7) Pub Date : 2024-05-15 Jialin Shi, Changxu Wu, Honglai Liu, Huazhou Li
The performance of the perturbed‐chain statistical associating fluid theory‐type equations of state (PC‐SAFT‐type EOSs) is compromised in predicting properties of pure compounds in the critical region. In our previous research, we introduced an improved volume‐translated rescaled PC‐SAFT EOS (VTR‐PC‐SAFT EOS) by incorporating a dimensionless distance‐function. Such VTR‐PC‐SAFT EOS is built based on
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Process safety 4.0: Artificial intelligence or intelligence augmentation for safer process operation? AlChE J. (IF 3.7) Pub Date : 2024-05-15 Rajeevan Arunthavanathan, Zaman Sajid, Md. Tanjin Amin, Yuhe Tian, Faisal Khan, Efstratios Pistikopoulos
The growth of artificial intelligence (AI) has allowed industries to automate and improve their efficiency in operations. Especially in process industries, AI helps to develop intelligent models and tools to proactively monitor and predict equipment or system failures, minimize downtime, and optimize maintenance schedules. With the advancements in AI and its ability to perform tasks, there is a growing
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De‐carboxylation of cross‐linkable triptycene‐based polyimides for CO2 separation AlChE J. (IF 3.7) Pub Date : 2024-05-15 Xiaoyu Wang, Fangxu Fan, Yongchao Sun, Jingfa Zhang, Canghai Ma, Gaohong He
Polymer‐based membrane technology holds immense promise for CO2 separation. However, it faces persistent challenges, including the high CO2 pressure‐induced plasticization and permeability‐selectivity trade‐offs, which significantly hinder the development of polymeric membranes. To tackle this issue, we synthesized a novel polyimide 6FDA‐DAT:DABA(6FDD) containing triptycene and carboxylic groups. Upon
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Hollow fiber membrane governed microjet flow regime for confined crystallization of large‐sized crystal aggregates AlChE J. (IF 3.7) Pub Date : 2024-05-15 Yuchao Niu, Shaofu Du, Shankun Liang, Lei Sheng, Yingshuang Meng, Wu Xiao, Xuehua Ruan, Gaohong He, Xiaobin Jiang
Confined crystallization can realize controllable nucleation and growth of crystals with targeted morphologies in a restricted region. Here, we achieved confined reactive crystallization within a novel micro columnar jet flow regime constructed by the hollow fiber membrane. The interface of the jet flow corresponds as the restricted region for reactive crystallization, and the large‐sized calcium carbonate
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Oxygen Isotopologues Resolved from Water Oxidation Electrocatalysis by Electron Paramagnetic Resonance Spectroscopy J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-14 Trisha T. Nguyen, Richard I. Sayler, Aaron H. Shoemaker, Jibo Zhang, Stefan Stoll, Jay R. Winkler, R. David Britt, Bryan M. Hunter
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An Unexpected Decrease in Vibrational Entropy of Multicomponent Rutile Oxides J. Am. Chem. Soc. (IF 15.0) Pub Date : 2024-05-14 Yaowen Wang, Xinbo Li, Jipeng Luo, Brian F. Woodfield, Xiyang Wang, Tao Feng, Nan Yin, Quan Shi, Guangshe Li, Liping Li