The study introduces a novel porous organic polymer, Fe(Cp)-POP, synthesized from ferrocene and s-triazine, and characterized through various analytical techniques such as FT-IR, Raman, XRD, XPS, UV–visible, SEM, HR-TEM, EDX, BET surface area analysis, TGA, photocurrent measurements, EIS, and CV. This photocatalyst exhibits reusability, contributing to by-products reduction and resource efficiency. The sustainable methodology adheres to green chemistry principles, promoting eco-friendly synthetic approaches. Fe(Cp)-POP was utilized in the photocatalytic reduction of nitroarenes to anilines, essential organic chemistry precursors, using NH and visible-light activation under mild conditions. The incorporation of porous organic polymers with a ferrocene framework displayed promising outcomes in enhancing the reduction of nitroarene compounds, with a focus on reducing the nitro-functional group in benzimidazole-based compound.

中文翻译：

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结合二茂铁和均三嗪的创新多孔有机聚合物：利用可见光将硝基芳烃转化为苯并咪唑的有效方法


该研究介绍了一种新型多孔有机聚合物 Fe(Cp)-POP，由二茂铁和均三嗪合成，并通过各种分析技术（如 FT-IR、拉曼、XRD、XPS、紫外可见、SEM、HR- TEM、EDX、BET 表面积分析、TGA、光电流测量、EIS 和 CV。这种光催化剂具有可重复使用性，有助于减少副产品和提高资源效率。可持续方法坚持绿色化学原则，推广生态友好的合成方法。 Fe(Cp)-POP 在温和条件下使用 NH 和可见光活化，将硝基芳烃光催化还原为苯胺（重要的有机化学前体）。将多孔有机聚合物与二茂铁骨架结合在增强硝基芳烃化合物的还原方面显示出有希望的结果，重点是减少苯并咪唑基化合物中的硝基官能团。